High-Purity Solvents, Personal Care

Hexadecyl Amine

Hexadecyl Amine (CAS: 143-27-1), also commonly referred to as cetylamine or 1-aminohexadecane, is a long-chain primary aliphatic amine derived from $C_{16}$ fatty acids. This compound is characterized by a saturated 16-carbon hydrophobic tail attached to a polar primary amino group. At room temperature, it typically appears as a white, waxy crystalline solid with a faint, characteristic ammoniacal odor.

As an amphiphilic molecule, hexadecyl amine serves as a versatile building block in chemical synthesis and surface science. It is primarily valued for its ability to modify surface tension and provide cationic functionality when neutralized or quaternized. In industrial settings, it acts as a precursor for surfactants, corrosion inhibitors, and specialty lubricants. Furthermore, its role in advanced materials science is significant; it is a standard capping agent in the synthesis of monodisperse nanoparticles and quantum dots, where it regulates crystal growth and prevents agglomeration. Due to its corrosive nature and toxicity to aquatic life, it requires stringent safety protocols during handling and disposal.

Attributes

Key Features and Benefits

  • High Surface Activity: Effectively reduces interfacial tension, facilitating the creation of stable emulsions and dispersions.
  • Strong Adsorption: The amino group exhibits high affinity for metallic and mineral surfaces, providing a robust hydrophobic barrier.
  • Chemical Versatility: Acts as a reactive intermediate for synthesizing quaternary ammonium compounds, betaines, and ethoxylated amines.
  • Thermal Stability: Demonstrates stability across a broad range of industrial processing temperatures, ensuring consistent performance in high-heat applications.
  • Excellent Lubricity: The long hydrocarbon chain provides inherent lubricating properties, reducing friction in mechanical and polymer systems.
  • Morphological Control: In nanotechnology, it offers precise control over the size and shape of nanocrystals during chemical vapor deposition or colloidal synthesis.
Specifications

Technical Highlights

  • Molecular Formula: $C_{16}H_{35}N$
  • Molecular Weight: 241.46 g/mol
  • Physical State: White waxy solid (at 20°C).
  • Melting Point: 43°C to 46°C (109°F to 115°F).
  • Boiling Point: 322°C (611.6°F) at 760 mmHg.
  • Solubility Profile: Insoluble in water ($<0.1$ mg/L); soluble in organic solvents such as ethanol, chloroform, and diethyl ether.
  • Purity: Commercial grades typically range from 90% (technical) to >98% (high-purity).
  • Safety Classification: Classified as Corrosive (Skin Cat. 1B) and Environmentally Hazardous (Aquatic Chronic 1).
  • Vapor Pressure: Extremely low at ambient temperatures, minimizing inhalation risk under normal storage.

Download Technical Data Sheet (TDS)

Practical industry uses

Applications

  • Nanomaterial Synthesis: Widely used as a capping ligand and solvent for producing semiconductor quantum dots (e.g., CdSe) and metal nanoparticles.
  • Corrosion Inhibition: Formulated into oilfield chemicals and boiler water treatments to protect ferrous metals from oxidative corrosion.
  • Mineral Processing: Functions as a cationic collector in froth flotation for the separation of silicate, potash, and phosphate minerals.
  • Textile and Plastic Additives: Used in the production of antistatic agents, fabric softeners, and internal lubricants for polymer processing.
  • Asphalt Emulsifiers: Enhances the adhesion between bitumen and mineral aggregates in road construction and paving applications.
  • Chemical Synthesis: Serves as a raw material for manufacturing biocides, fungicides, and specialized surfactants.
Key Sectors

Target Industries

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